ITM Web Conf.
Volume 12, 2017The 4th Annual International Conference on Information Technology and Applications (ITA 2017)
|Number of page(s)||6|
|Section||Session 4: Information Theory and Information Systems|
|Published online||05 September 2017|
Hydrophobic Lurylamine Modified Heteropoly Acid as an Efficient and Recyclable Catalyst for the Hydrolysis Reaction in Aqueous Solution under Microwave
Qingdao Technical College, Qingdao, Shandong Province
A new modified phosphotungstic acid (HPW) catalyst (HPW-catal) was synthesized b y a simple mixing method under ambient atmosphere and evaluated for the hydrolysis of sucrose and ethyl acetate under microwave irradiation. The as-synthesized catalyst was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy(FTIR), and NH3-TPD, which proved that HPW was sucessfully modified with lurylamine and the catalyst still remains the Keggin structure. Significantly, the HPW-catal showed excellent catalytic hydrolysis perforance for the sucrose and ethyl acetate under microwave irradiation. Both of the reactions were studied over other solid acid catalysts, such as AM-15 and ZSM-5. At mild tempretures, the sucrose and ethyl acetate could be hydrolyzed into corresponding products. The maximum glucose yield and alcohol could reach 100% and 95%, respectively. The HPW-catal can be recycled and reused. The HPW-catal will provides new ideas for the modifying of heteropoly acids.
© The Authors, published by EDP Sciences, 2017
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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